10 Dangerous Experiments That Demand a Laboratory Hood

Have you ever felt the strange smell of ammonia vapors or the stinging sensation of HCl fumes? Bad news—not only is the smell disgusting, but the vapors can also harm the lining of your nose and damage your lungs and respiratory system. Seeing this problem, chemists developed the laboratory hood, or fume hood, in the early 20th century. Since then, it has been the gold standard in laboratories that work with chemical substances releasing toxic fumes, vapors, or particles that can harm the user.

Who needs the laboratory hood?

Laboratory hoods are needed where toxic vapors, flammable gases or disturbing odors are released as a result of chemical experimentation
Laboratory hoods are needed where toxic vapors, flammable gases or disturbing odors are released as a result of chemical experimentation

Schools, colleges, research institutes, and industries that work with chemicals that are volatile, have low boiling points, and produce toxic vapors and fumes need to install laboratory or fume hoods. These filter and purify the air, emitting it outside or recirculating it into the lab. They absorb air from inside and around the fume hood when switched on. Even when the laboratory hood sash is closed, it can still pull in and purify air.

Which experiments need to be performed inside a laboratory hood?

Schools, colleges, research institutes and industries have separate categories of experiments that need a laboratory hood. 

A standard laboratory hood
A standard laboratory hood

Laboratory Hoods for School Experiments

Schools normally follow a syllabi such that lab experiments are relatively safe. However, some experiments need to be performed inside a fume hood, especially since young children and relatively untrained students are involved. 

Neutralization reactions

this is the mechanism of hydrochloric acid and sodium hydroxide reacting to produce salt and water. the proton from HCl abstracts the hydroxyl from sodium hydroxide. the sodium and chloride ions stay together to form the salt.
HCl and NaOH react to produce water and sodium chloride.

HCl (aq) + NaOH (aq) → NaCl (aq) + H₂O (l)​

Dangers: HCl (aq) often emits acidic fumes that are harsh on the respiratory epithelium of the nose and lungs. Hence, laboratory hoods can be used to minimize the amount of HCl vapour inhaled by students during chemistry practicals.

Displacement reactions

Zn (s) + 2HCl (aq) → ZnCl₂ (aq) + H₂ (g)​

Dangers: The issue of HCl vapors persists here. The H₂ gas that is emitted is flammable and cannot be allowed to accumulate inside the chemistry lab. 

Combustion reactions

Flammable methane reacts with oxygen to form carbon dioxide and water
Flammable methane reacts with oxygen to form carbon dioxide and water

CH₄ (g) + 2O₂ (g) → CO₂ (g) + 2H₂O (g)​

Dangers: Methane is highly flammable. This reaction should be conducted with complete precautions, such as a controlled supply of methane before combustion, proper dispersal, and ventilation in case of leakage. Regular checks are necessary to ensure that accidental leaks do not occur when no one is watching.

Additionally, the CO₂ formed is toxic if it accumulates inside the lab. It displaces oxygen and makes breathing difficult. When multiple students perform the experiment, a large amount of CO₂ will accumulate inside the lab, causing suffocation. Hence, it must be performed inside a laboratory hood.

Laboratory Hoods for Research Institutes

Research institutes deal with reactions that are generally not demonstrated at the school level. Some of these reactions can be dangerous, others emit toxic or flammable fumes necessitating fume hoods. 

Oxidation of Organic Compounds​

Oxidation of toluene with potassium permanganate forms benzoic acid
Oxidation of toluene with potassium permanganate forms benzoic acid

C₆H₅CH₃ (toluene) + KMnO₄(HCl) → C₆H₅COOH (benzoic acid)​

Dangers: Toluene is highly flammable, irritant to the skin and mildly toxic when inhaled. Hydrochloric Acid is corrosive and releases HCl gas that is also corrosive. Hence, laboratory hoods can benefit scholars working in these settings. 

Grignard Reactions​

The Grignard reaction takes place in two steps: nucleophilic attack and hydrolysis
The Grignard reaction takes place in two steps: nucleophilic attack and hydrolysis

RMgX + R’COR” → R’R”RCOMgX
R’R”RCOMgX + H₂O → R’R”RCOH + Mg(OH)X

Dangers: Grignard reagents are dissolved in highly flammable ethers. The alkanes released are sometimes flammable. Hence the fume hood serves to remove alkane vapors from the lab. This reduces the chance of fire hazards. 

Diazotization Reactions​

Diazotization reaction of aniline forms benzene diazonium chloride
Diazotization reaction of aniline forms benzene diazonium chloride

ArNH₂ + NaNO₂ + HCl → ArN₂⁺Cl⁻ + 2H₂O​

Dangers: Certain conditions can produce nitrogen oxides (NOₓ), which are harmful when inhaled, as well as hydrochloric acid (HCl) vapors. These can be dissipated and safely vented using a laboratory hood.

Laboratory Hoods for Industrial and R&D Laboratories

Industrial labs usually test reactions in the R&D lab before scaling up to large-scale setups. This process is dangerous because, many times, the exact reaction dynamics and outcomes may not be known beforehand. Theoretically, some reactions can be performed more safely in fume hoods.

Chlorination Reactions​

Chlorination reaction of benzene forms chlorobenzene in a laboratory hood
Chlorination reaction of benzene forms chlorobenzene

C₂H₄ + Cl₂ → C₂H₄Cl₂​

Dangers: Chlorine must be handled carefully. The vapour is extremely toxic and can cause respiratory damage. Laboratory hoods can remove the vapours from the air, if excess chlorine is dissipated inside the lab. 

Nitration of Aromatic Compounds​

C₆H₆ + HNO₃ → C₆H₅NO₂ + H₂O​

Dangers: Nitric and hydrochloric acids are used in this reaction. Both emit acidic pungent vapours that must be safely handled inside the laboratory hood. 

Polymerization of Acrylates​

Methyl methacrylate polymerization using the free radical mechanism in a laboratory hood
Methyl methacrylate polymerization using the free radical mechanism

n CH₂=CHCOOCH₃ → [CH₂-CH(COOCH₃)]ₙ​

Dangers: Methyl methacrylate vapors are heavier than air. They can settle down and cause difficulty in breathing due to irritation in the respiratory system. They can also cause irritation in the eyes and on the skin. It is highly flammable when mixed with air, with a closed cup flash point of 2°C. 

More Actions

Frequently Asked Questions (FAQs)

Which chemical is dangerous in the laboratory?

A list of dangerous chemicals found in the lab according to MIT are:

  • Arsenic trioxide
  • Chlorine
  • Hydrogen cyanide
  • Nitrous oxide
  • Phosgene
  • Potassium cyanide (analytical reagent and purified)
  • Sodium arsenate (analytical reagent)
  • Sodium cyanide (analytical reagent)

For experiments with chlorine or nitrous oxide, a laboratory hood must be used. 

What is a dangerous science experiment in school?

A dangerous science experiment is one where safety hazards, such as toxic substances, flammable materials, or high temperatures, can lead to harm if proper precautions are not followed. One example of a risky science demonstration is the Rainbow Flame Demonstration, where different salts are mixed with ethanol or methanol to produce colored flames.

Methanol, commonly used in such demonstrations, is highly toxic by inhalation and skin contact. It also releases heavy vapors that can travel long distances and has a dangerously low flash point. When working with methanol, you may use a laboratory hood. 

Get in Touch

Comments

Leave a Reply

Your email address will not be published. Required fields are marked *

Suggested Reads

Get in Touch

  • 10 Dangerous Experiments That Demand a Laboratory Hood
  • Essential Biology Lab Furniture Guide
  • 6 Essential Lab Furniture Items You Need
  • Choose the Perfect Lab Table for Your Lab
  • Finding Your Lab Furniture Manufacturer: Mistakes You Can’t Afford
  • Physics Lab in a Box for Coaching Centers in India
  • Hands-On Homeschooling Resource: The Physics Lab in a Box
  • Physics Lab in a Box: Demonstrate School Physics Practical Without a Lab
  • Laboratory Thermometer: Diagram, Range, and Functions Explained
  • Maintain School Biology Lab: Essential Tips & Best Practices
  • Step by Step Guide to Maintain the School Chemistry Lab 
  • How To Maintain the School Physics Lab- 5 Step Guide